Hexylamine
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Material Safety Data Sheet
Hexylamine
Section 1 - Chemical Product and Company Identification
MSDS Name: Hexylamine
Catalog Numbers:SC-79034
Section 2 - Composition, Information on Ingredients
CAS#111-26-2
Chemical Name: Hexylamine
Percent 98%
EINECS/ELINCS: 203-851-8
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 3), H226
Acute toxicity, Oral (Category 3), H301
Acute toxicity, Dermal (Category 3), H311
Skin corrosion (Category 1A), H314
For the full text of the H-Statements mentioned in this Section, see Section 16.
Classification according to EU Directives 67/548/EEC or 1999/45/EC
C Corrosive R10, R21/22, R35
For the full text of the R-phrases mentioned in this Section, see Section 16.
2.2 Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram
Signal word Danger
Hazard statement(s)
H226 Flammable liquid and vapour.
H301 + H311 Toxic if swallowed or in contact with skin
H314 Causes severe skin burns and eye damage.
Precautionary statement(s)
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physician.
Supplemental Hazard Statements none
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
May cause irritation to eyes, respiratory system and skin.
Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion: May be harmful if swallowed.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Limited evidence of a carcinogenic effect.
Section 4 - First Aid Measures
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and water.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: May be harmful if inhaled. Material may be irritating to mucous membranes and upper respiratory tract.
Notes to Physician: Treat symptomatically and supportively
Section 5 - Fire Fighting Measures
5.1 Extinguishing media
Suitable extinguishing media
For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply water from as far as possible. Use verylarge
quantities (flooding) of water applied as a mist or spray; solid streams of water may be ineffective. Cool all affected containers with flooding quantities of
water.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, nitrogen oxides (NOx)
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Do not let this chemical enter the environment.
Section 7 - Handling and Storage
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.
Sensitive to carbon dioxide Air sensitive.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to
keep airborne concentrations low.
Personal Protective Equipment
Eyes: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Normal
measures for preventive fire protection.
Skin: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin
contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Clothing: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respirators:Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Section 9 - Physical and Chemical Properties
Physical State: Liquid.
Color:Colorless.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 131 - 132 °C - lit.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available
Flash Point: 27 °C - closed cup
Decomposition Temperature: Not available.
Water Solubility: Not available.
Specific Gravity/Density: Not available.
Molecular Formula:C6H15N .
Molecular Weight:101.19 .
Section 10 - Stability and Reactivity
Chemical Stability: Not available.
Conditions to Avoid: Not available.
Incompatibilities with Other Materials: acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents, Carbon dioxide (CO2)
Hazardous Decomposition Products: Not available.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
RTECS#: MQ4540000.
CAS#111-26-2.
LD50/LC50: RTECS:MQ4540000.
Carcinogenicity:
Hexylamine ,98%- Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Other Studies: The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information.
Section 12 - Ecological Information
12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 56,6 mg/l - 96 h
Toxicity to daphnia and other aquatic EC50 - Daphnia magna (Water flea) - 8,6 mg/l - 48 h
invertebrates
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
Toxic to aquatic life.
no data available
Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product: Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer
surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging: Dispose of as unused product.
Section 14 - Transport Information
14.1 UN number
ADR/RID: 2734 IMDG: 2734 IATA: 2734
14.2 UN proper shipping name
ADR/RID: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Hexylamine)
IMDG: AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Hexylamine)
IATA: Amines, liquid, corrosive, flammable, n.o.s. (Hexylamine)
14.3 Transport hazard class(es)
ADR/RID: 8 (3) IMDG: 8 (3) IATA: 8 (3)
14.4 Packaging group
ADR/RID: I IMDG: I IATA: I
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
no data available
Section 15 - Regulatory Information
European Labeling in Accordance with EC Directives
Hazard Class:C,F,Xi
Risk Phrases:
R10 Flammable.
R21/22 Harmful in contact with skin and if swallowed.
R35 Causes severe burns
Safety Phrases:
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities
from the use of this product or information contained herein.
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