1-Bromopropane
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Material Safety Data Sheet
1-Bromopropane
Section 1 - Chemical Product and Company Identification
MSDS Name: 1-Bromopropane
Catalog Numbers: SC-22644
Section 2 - Composition, Information on Ingredients
CAS# 106-94-5
Chemical Name: 1-Bromopropane
Percent 98%
EINECS/ELINCS: 203-445-0.
Section 3 - Hazards Identification
3.1 Classification of the substance or mixture
Flammable liquids (Category 2), H225
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319
Carcinogenicity (Category 2), H351
Reproductive toxicity (Category 1B), H360FD
Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Specific target organ toxicity - repeated exposure (Category 2), H373
Chronic aquatic toxicity (Category 3), H412
Hazardous to the ozone layer (Category 1), H420
For the full text of the H-Statements mentioned in this Section, see Section 16.
3.2 Label elements
Labelling according Regulation (EC) No 1272/2008 [CLP]
Pictogram
Signal word Danger
Hazard statement(s)
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H360FD May damage fertility. May damage the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
H420 Harms public health and the environment by destroying ozone in the upper atmosphere.
Precautionary statement(s)
P201 Obtain special instructions before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P370 + P378 In case of fire: Use dry powder or dry sand to extinguish.
P403 + P235 Store in a well-ventilated place. Keep cool.
Supplemental Hazard Statements none
3.3 Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Section 4 - First Aid Measures
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician
Section 5 - Fire Fighting Measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen bromide gas
5.3 Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary
5.4 Further information
no data available
Section 6 - Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
6.4 Reference to other sections
For disposal see section 13.
Section 7 - Handling and Storage
7.1 Precautions for safe handling
Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Recommended storage temperature: 2 - 8 °C
Section 8 - Exposure Controls, Personal Protection
Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection
Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Section 9 - Physical and Chemical Properties
Physical State: clear, liquid
Color: light brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Melting point: Not available.
Autoignition Temperature: Not available
Flash Point: Not available
Explosion Limits: Not available.
Explosion Limits: Not available.
Decomposition Temperature: Not available.
Specific Gravity/Density: Not available
Molecular Formula: C3H7Br
Molecular Weight: 122.99
Section 10 - Stability and Reactivity
10.1 Reactivity
no data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
no data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
no data available
10.6 Hazardous decomposition products
Other decomposition products - no data available
In the event of fire: see section 5
Section 11 - Toxicological Information
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - male - 4.260 mg/kg
LC50 Inhalation - Rat - male and female - 4 h - 14374 ppm
(OECD Test Guideline 403)
LD50 Dermal - Rabbit - male and female - 135.000 mg/kg
(OECD Test Guideline 402)
LD50 Intraperitoneal - Rat - 2.950 mg/kg
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
Eyes - Rabbit
Result: Irritating to eyes.
Respiratory or skin sensitisation
Maximisation Test (GPMT) - Guinea pig
Result: Does not cause skin sensitisation.
(OECD Test Guideline 406) Germ cell mutagenicity
no data available
Carcinogenicity
Carcinogenicity - Rat - male and female - inhalation (vapour)
Skin and Appendages: Other: Tumors. Lungs, Thorax, or Respiration:Tumors.
Suspected human carcinogens
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
Reproductive toxicity - Rat - male and female - inhalation (vapour)
Paternal Effects: Spermatogenesis (including genetic material, sperm morphology,motility, and count).
Presumed human reproductive toxicant
Specific target organ toxicity - single exposure
inhalation (vapour) - May cause damage to organs through prolonged or repeated exposure. - Liver,
Central nervous system
Inhalation - Liver
Inhalation - Central nervous system
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: TX4110000
Section 12 - Ecological Information
12.1 Toxicity
Toxicity to fish semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 24,3 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 99,3 mg/l - 48 h
(OECD Test Guideline 202)
Toxicity to algae static test NOEC - Pseudokirchneriella subcapitata - 12,4 mg/l - 96 h (OECD Test Guideline 201)
Toxicity to bacteria Respiration inhibition EC50 - Sludge Treatment - 270 mg/l - 5 min
12.2 Persistence and degradability
Biodegradability aerobic - Exposure time 28 d
Result: 19,2 % - Not readily biodegradable.
(OECD Test Guideline 301D)
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
12.6 Other adverse effects
no data available
Section 13 - Disposal Considerations
13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.
Section 14 - Transport Information
14.1 UN number
ADR/RID: 2344 IMDG: 2344 IATA: 2344
14.2 UN proper shipping name
ADR/RID: BROMOPROPANES
IMDG: BROMOPROPANES
IATA: Bromopropanes
14.3 Transport hazard class(es)
ADR/RID: 3 IMDG: 3 IATA: 3
14.4 Packaging group
ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
14.6 Special precautions for user
No data available
Section 15 - Regulatory Information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Authorisations and/or restrictions on use
1-Bromopropane CAS-No.: 106-94-5
REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).
Toxic for reproduction (article 57c)
1-Bromopropane CAS-No.: 106-94-5
REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous
substances, preparations and articles (Annex XVII)
Toxic to reproduction: category 1B
Restricted to professional users.
See Annex XVII to Regulation (EC) no 1907/2006 for Conditions of restriction
1-Bromopropane CAS-No.: 106-94-5
Regulation (EC) No 1005/2009 on substances that deplete the ozone layer
Ozone depletion potential; ODP; (R-11 = 1): 0,02 - 0,1
15.2 Chemical Safety Assessment
For this product a chemical safety assessment was not carried out
Section 16 - Additional Information
Full text of H-Statements referred to under sections 2 and 3.
H225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H351 Suspected of causing cancer.
H360FD May damage fertility. May damage the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
H420 Harms public health and the environment by destroying ozone in the upper atmosphere.
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.
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