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2-Amino-1,3-propanediol

Material Safety Data Sheet
2-Amino-1,3-propanediol
Section 1 - Chemical Product and Company Identification
MSDS Name: 2-Amino-1,3-propanediol
Catalog Numbers: 86-15765

Section 2 - Composition, Information on Ingredients 
CAS# 534-03-2
Chemical Name: 2-Amino-1,3-propanediol
Percent  98.0%min
EINECS/ELINCS:208-584-0
Hazard Symbols: C
Risk Phrases: 34

Label elements
Labelling according Regulation (EC) No 1272/2008
Pictogram   
Signal word: Danger
Hazard statement(s)
H314: Causes severe skin burns and eye damage.
Precautionary statement(s)
P280: Wear protective gloves/ protective clothing/ eye protection/ face

Section 3 - Hazards Identification 
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Light sensitive.

Potential Health Effects
Inhalation: May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion: May be harmful if swallowed.
Skin: May be harmful if absorbed through skin. Causes skin irritation.
Eyes: Causes serious eye irritation
Chronic:

Section 4 - First Aid Measures
4.1 Description of first aid measures
General advice: Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician.
In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed: no data available

Section 5 - Fire Fighting Measures 
5.1 Extinguishing media
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture: Carbon oxides, nitrogen oxides (NOx)
5.3 Advice for firefighters: Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Further information: no data available

Section 6 - Accidental Release Measures 
6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.
6.2 Environmental precautions: Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up: Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed  containers for disposal.
6.4 Reference to other sections: For disposal see section 13.

Section 7 - Handling and Storage 
7.1 Precautions for safe handling
Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Hygroscopic. Store under inert gas. Sensitive to carbon dioxide strongly hygroscopic
7.3 Specific end use(s): A part from the uses mentioned in section 1.2 no other specific uses are stipulated

Section 8 - Exposure Controls, Personal Protection 

8.1 Control parameters: Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls: Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.

Personal protective equipment
Eye/face protection: Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and  the standard EN 374 derived from it.
Body Protection: Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure: Do not let product enter drains.

Section 9 - Physical and Chemical Properties 
Physical State: powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 277 °C at 1.013 hPa
Melting point: 52 - 55 °C
Autoignition Temperature: Not available
Flash Point: 113 °C - closed cup
Explosion Limits: Lower: Not available
Explosion Limits: Upper: Not available
Decomposition Temperature:Not available.
Solubility: no data available
Specific Gravity/Density: 
Molecular Formula: C3H9NO2
Molecular Weight: 91.11

Section 10 - Stability and Reactivity 
Chemical Stability: Stable under recommended storage conditions.
Conditions to Avoid:Avoid moisture.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, hydrogen iodide.
Hazardous Polymerization:Has not been reported.

Section 11 - Toxicological Information
RTECS#: CAS# 534-03-2 : None listed     
LD50/LC50: RTECS: Not available.
Carcinogenicity:
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Other Studies: The toxicological properties have not been fully investigated.
Additional Information
RTECS: Not available
Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and  skin., Cough, Shortness of breath, Headache, Nausea

Section 12 - Ecological Information 
Not available
Results of PBT and vPvB assessment: PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Section 13 - Disposal Considerations 
Waste treatment methods
Product: Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging: Dispose of as unused product.

Section 14 - Transport Information 
14.1 UN number
ADR/RID: 3263                                        IMDG: 3263                                 IATA: 3263
14.2 UN proper shipping name
ADR/RID:  CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2-Aminopropane-1,3-diol)
IMDG:  CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (2-Aminopropane-1,3-diol)
IATA:  Corrosive solid, basic, organic, n.o.s. (2-Aminopropane-1,3-diol)
14.3 Transport hazard class(es)

ADR/RID: 8                                              IMDG: 8                                       IATA: 8
14.4 Packaging group
ADR/RID: II                                              IMDG: II                                       IATA: II
14.5 Environmental hazards
ADR/RID: no                                             IMDG Marine pollutant: no           IATA: no
14.6 Special precautions for user
no data available

Section 15 - Regulatory Information 
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Chemical Safety Assessment
For this product a chemical safety assessment was not carried out

European/International Regulations
      Full text of H-Statements referred to under sections 2 and 3.
                 H314 Causes severe skin burns and eye damage.
                 Skin Corr. Skin corrosion
      Full text of R-phrases referred to under sections 2 and 3
                 C Corrosive
                 R34 Causes burns.

Section 16 - Additional Information
While the information herein is believed to be reliable, it is furnished without warranty of any kind. It shall be used only as a guide. We assume no liabilities from the use of this product or information contained herein.